Electrolyte Highway Breakthrough Unlocks Affordable Low-Temperature Hydrogen Fuel (interestingengineering.com)
- Reference: 0178649786
- News link: https://science.slashdot.org/story/25/08/12/0412223/electrolyte-highway-breakthrough-unlocks-affordable-low-temperature-hydrogen-fuel
- Source link: https://interestingengineering.com/energy/electrolyte-highway-unlocks-affordable-hydrogen
> "While SOFCs are promising due to their high efficiency and long lifespan, one major drawback is that they require operation at high temperatures of around 700-800C (1292F-1472F)," added the researchers in a [2]press release . Such heat requires costly, specialized heat-resistant materials, making the technology expensive for many applications. A lower operating temperature is expected to reduce these manufacturing costs.
>
> The team's success comes from re-engineering the fuel cell's electrolyte, the ceramic layer that transports protons (hydrogen ions) to generate electricity. Previously, scientists faced a trade-off. Adding chemical dopants to an electrolyte increases the number of available protons but also tends to clog the material's crystal lattice, slowing proton movement and reducing performance. The Kyushu team worked to resolve this issue. "We looked for oxide crystals that could host many protons and let them move freely -- a balance that our new study finally struck," stated Yamazaki.
>
> They found that by doping two compounds, barium stannate (BaSnO3) and barium titanate (BaTiO3), with high concentrations of scandium (Sc), they could create an efficient structure. Their analysis showed that the scandium atoms form what the researchers call a "ScO6 highway." This structure creates a wide and softly vibrating pathway through the material. "This pathway is both wide and softly vibrating, which prevents the proton-trapping that normally plagues heavily doped oxides," explained Yamazaki. The resulting material achieves a proton conductivity of more than 0.01 S/cm at 300C, a performance level comparable to conventional SOFC electrolytes that run at more than double the temperature.
The research has been [3]published in the journal Nature Materials .
[1] https://interestingengineering.com/energy/electrolyte-highway-unlocks-affordable-hydrogen
[2] https://www.kyushu-u.ac.jp/en/researches/view/346
[3] https://www.nature.com/articles/s41563-025-02311-w
Wrong wrong wrong (Score:3, Insightful)
"300C, less than half the usual operating temperature"
If you're going to add editorial comments, get an editor who knows some physics.
Re: (Score:2, Flamebait)
From a purely numeral point of view, it's correct, as 300 is less than a half of 650. It just does not mean that the normal operating temperature of fuel cells is "twice as hot", or as my father used to say: "The only thing hot is the old woman's coffee."
Re: (Score:2)
The only thing hot is the old woman's coffee."
If your coffee is 300C, you are in trouble..
Re: (Score:3)
If you got served by [1]McDonald's [wikipedia.org], it might hurt at first, but you could be fine in the long run.
[1] https://en.wikipedia.org/wiki/Liebeck_v._McDonald's_Restaurants
Re: (Score:1)
Perhaps you should learn to recognise colloquialisms. To 99.99% of people 300 is less than half of 700. No one measures in kelvins outside of the lab.
Re: (Score:3)
In C it's half. In F it's only 20%. Still sloppy journalism.
But there are bigger issues, the headline mentions hydrogen fuel but the article does not relate to actual hydrogen production.
Re: (Score:2)
"In C it's half. In F it's only 20%"
Irrelevant, both temps were written in C, not F.
"Still sloppy journalism."
If you want precise physical measures read Nature.
Re: (Score:2)
We are the lab and we don't measure anything in Kelvins either.
Re: Wrong wrong wrong (Score:2)
There's more. In TFA, it says 300ÂC is 500ÂF. (It's 572ÂF.)
Re: (Score:2)
it's wrong, but essentially correct. The important figure here is the distance from "room temperature", because that's what thermal dissipation depends on. You get technical when deciding on the materials to use, etc., but this isn't about that (except for the claim that they could use cheaper materials).
After 40 years (Score:3)
So after 40 years they have improved the fuel cell. Now they just need to solve the issues with the cost of green hydrogen, the cost of shipping it, the cost of storing it and the cost of HFCVs.
Re:Closer to 140 years (Score:2)
From Wikipedia's Fuel Cell article:
> The first fuel cells were invented by Sir William Grove in 1838. The first commercial use of fuel cells came almost a century later following the invention of the hydrogen–oxygen fuel cell by Francis Thomas Bacon in 1932.
This has been a LONG time coming! Also, unless I'm missing something, this lower-temp SOFC can also be fueled with hydrocarbons not just plain hydrogen gas.
Finally, this is the same temperature as the Sodium-Sulfur battery, so keeping it hot is NOT t
Just one of many, many, many problems with hydroge (Score:3)
Hydrogen is just an excuse by Big Oil to pump gas and oil as usual...
It has way to many issues to be viable in the near future - power cells are only one, storing, generation, transport - it is all much more difficult than alternatives.
Compare how sending electricity 100km compares to transporting hydrogen...
It is great to have some progress as for sure it will have some uses somewhere... but for 95% of people EVs are way to go...
Re: Just one of many, many, many problems with hyd (Score:2)
Sending electricity 100km, whatever made up ass units those are is trivial because there's a pipe for that already, nearly universally. Hydrogen doesn't have a pipe installed yetz and they shouldn't make one.
Re: (Score:2)
These cells are made with another hard to find rare earth, Scandium.
Re: (Score:2)
Good band name.
Re: (Score:2)
Hard to produce. Scandium is relatively abundant but there are no scandium ores anywhere. No natural process concentrates it. It is produced solely as a byproduct of other mining operations and global production annually is only about 40 tons. In comparison rare earth production in total is 350,000 tons. This is one of the lowest quantities of any element that is mineable at all.
So they could scarcely have picked a worse element to have as the essential ingredient.
Re: (Score:1)
> It has way to many issues to be viable in the near future - power cells are only one, storing, generation, transport - it is all much more difficult than alternatives.
This device works in reverse too, taking in power to produce hydrogen. I'm thinking that's a far more valuable application than as a power source.
> Hydrogen is just an excuse by Big Oil to pump gas and oil as usual...
A quick search of the web tells me about 15% of petroleum ends up as non-fuel products like lubricants, coolants, waxes, tars, asphalt, coke, and plastics. While they do a lot of cracking of hydrogen atoms off of carbon atoms to produce hydrogen for varied uses they also take hydrogen atoms to stick to carbon atoms, and other atoms like nitrogen. This was even
Re: (Score:2)
> The petroleum industry has to see that the future in drilling isn't all that bright. They've been making a good business out of producing chemicals.
But a fraction of the business of producing it for fuel. No industry operates on a "lets downsize by 85% over the next 50 years" plan, even if that is really necessary for everyone but their stock owners / executives.The farther they can push off the inevitable the more money ends up in the pockets of the people making all the decisions.
Re: (Score:2)
Like you, I'm all for improving Hydrogen technology. I still don't understand why we aren't cracking H2 out of the excess methane that is currently "flared" off of the remote NG pump sites. I'm not certain the exact process, but in places like West Texas it sure seems like we could park a windmill next to it to provide the power, eliminating the need for extending the power grid all the way out there, or even running a pipeline although you'd have to transport the H2 eventually.
The real problem I see with
Re: (Score:2)
> I still don't understand why we aren't cracking H2 out of the excess methane that is currently "flared" off of the remote NG pump sites.
This is very simple. It's not profitable to capture and transport the methane from those sites. It would be even more expensive to capture it, make hydrogen from it, and transport the hydrogen.
So drive with 300C / 572F fuel, no thanks. (Score:2, Insightful)
Who in their right mind would think that is a good idea.
Oil and gas companies (Score:2)
Its just makes it slightly easier for them to push their nonsense about hydrogen being a green fuel when in some cases its even worse than hydrocarbons for well (if its streamed from gas) to wheel CO2 released per BTU.
Re: (Score:2)
It doubles as an oven!
With the appropriate heat dissipation, you can cook a thanksgiving dinner under the hood of your truck on the way to grandma's house.
Re: (Score:3)
Internal parts of a gasoline engine routinely reach over 300C in normal operation. The combustion event itself can hit something like 2500C.
The temperature isn't really an issue.
=Smidge=
Re: (Score:3)
The top of a piston usually operates at under 300C (the gases, of course, are hotter). Only the exhaust system gets hotter than that.
Re: (Score:2)
Up until now, hydrogen people were talking about 10,000 psi tanks of hydrogen - because that's the point where the energy density starts to match petroleum fuels.
The question is really, why would we ever care about commerical hydrogen at all, when we have electric batteries pretty sewn up for now.
I can power my house and my car off a battery not much bigger than the filing cabinet sitting next to me now. What makes anyone think we need to worry about anything but shrinking that down a little more?
Re: (Score:2)
Batteries are probably approaching their limit. I doubt that another factor of 2 reduction in size/power is possible. Super capacitors seem to have stalled out (probably on fabrication problems). I haven't heard anything about hydrogen storage in zeolites for a decade (of course I haven't been looking). Wireless power transmission pretty much needs to be point-to-point, or there's no way to bill for it.
OTOH, we really need a good power store that doesn't release carbon dioxide. All I've been able to th
Does it really? (Score:2)
All of the problems of hydrogen are still there - blue hydrogen is a byproduct of fossil fuel extraction, green hydrogen requires 3x as much energy as charging a battery, it's dangerous to store, it's very expensive even compared to petroleum and offgassing harms the environment. But hooray some lab has made the process of converting hydrogen back to energy slightly less ruinous. I wonder who funded this research.
Re: (Score:2)
Normal batteries can't fuel of the energy requirement for aviation and shipping. Primary metal air batteries could in theory, but you need electrolysis to recycle those too after they are spent, at equally poor efficiency.
As for synthetic fuel, that would have to compete with plain hydrogen and in many niches would lose the fight. Hydrogen forklifts prove the problems are somewhat exagerated.
Re: Does it really? (Score:3)
Oil executives and the Toyota executives they've had a gun trained on for the past.. decades
Nope (Score:2, Insightful)
Stfu with the hydrogen distraction bullshit
But wait, there's more! "Valuable chemicals." (Score:1)
From the fine article: "reactors that convert CO2 into valuable chemicals"
What kind of "valuable chemicals" would those be? Octane? Cetane? Methane? Propane? That's what comes to mind for me.
Whenever hydrogen fuel cells are discussed on Slashdot I'll see numerous people jump to conclude the intended target is for vehicles. In my mind if it is for vehicles then it is for space vehicles, not something for the average commute or for any kind of over the road travel. If you have hydrogen and you need it
Re: (Score:2)
Could be used for forklifts in 24/7 applications, the need for the fuel cell to heat up isn't really relevant if it runs continuously.
Even though it's not a proper application, it might be used for some experimental class in LeMans. SOFC can more easily be used for extreme power densities than PEM.
Funny Yesterday this (Score:2)
[1]Hydrogen Dreams Fading [slashdot.org]
[1] https://hardware.slashdot.org/story/25/08/11/1814206/americas-clean-hydrogen-dreams-are-fading-again
Re: (Score:3)
The headline is misleading.
This research relates to making hydrogen fuel cells more affordable and practical.
Hydrogen fuel cells turn hydrogen and oxygen into water and electricity.
The production of hydrogen is still the bottleneck and the tech in TFA does not change that.
Re: (Score:2)
It could be used in a high pressure electrolysis cell, those need proton exchange too. Shame it need Scandium.
Re: (Score:3)
> [1]Hydrogen Dreams Fading [slashdot.org]
Hydrogen is eventually coming one day. Just not for cars. Your grandkids will probably fly on airliners running hydrogen fuel, and there will probably be big power generation facilities running it. But running it on common automobiles cheaply and efficiently is just too big a hump to get over. It's a lot easier for an airport to manage hydrogen than a gas station on the Interstate. As the Japanese have proved, you can do hydrogen automobiles, it's just really, really impractical at that vehicle size. Kind o
[1] https://hardware.slashdot.org/story/25/08/11/1814206/americas-clean-hydrogen-dreams-are-fading-again
Re: (Score:2)
That point may come. I'm no expert but I'm going with: at least not in the first 50 years.
Production of hydrogen is the problem.
By far most hydrogen produced today is made from fossil fuels and is equally polluting.
A much smaller part of it is made by electrolysis, which is very wasteful and results in hydrogen that is 3 times as expensive as that made from methane.
So with current tech we would need massive amounts of excess green electricity to make hydrogen a better option than ICEs and BEVs.
This is besid
Re: (Score:2)
> Hydrogen is eventually coming one day. Just not for cars. Your grandkids will probably fly on airliners running hydrogen fuel, and there will probably be big power generation facilities running it.
Airplanes are at least plausible. However, the volumetric energy density sucks, coming in at just 5.6 MJ/L unless you store it cryogenically, which isn't realistic in an airplane, compared with about 35 MJ/L for jet fuel. So if you're burning it, you'd have to increase the size of the fuel tanks by 6x. Fuel cells running electric fans are probably more efficient, and that efficiency difference might reduce that number somewhat, but probably not to break-even levels. Realistically, the efficiency differe
Re: (Score:2)
>> [1]Hydrogen Dreams Fading [slashdot.org]
> Hydrogen is eventually coming one day. Just not for cars. Your grandkids will probably fly on airliners running hydrogen fuel, . . .
Hindenburg. I believe it was called the Hindenburg.
[1] https://hardware.slashdot.org/story/25/08/11/1814206/americas-clean-hydrogen-dreams-are-fading-again